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The harsh acidic environment of the stomach can break down glutathione molecules before they have a chance to be absorbed

Kuo, H.-C

Wheat peptides reduce oxidative stress and inhibit NO production through modulating mu-opioid receptor in a rat NSAID-induced stomach damage model

But you're essentially burning substrate, so who cares

Plant and green algae extract, which are both physiologically safe and economically sustainable, have demonstrated a great deal of promise for crop enhancement in moderate-stress conditions in recent years 13

If you want a deeper look at the science behind this molecule, Understanding How Glutathione Works in Our Body is a helpful next read