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Several metal-based nanoparticles harboring multivalent elements, such as Cu 2+ /Cu + , Mn 4+/3+ /Mn 2+ , Mo 6+ /Mo 4+ , and Ir 4+ /Ir 3+ , possess strong oxidization, and can directly react with GSH (Nie et al., 2022)

Because longterm human studies are lacking, there are concerns about unknown immune, cardiovascular, or proliferative effects, and some experts warn that users may face unpredictable risks, especially with unsupervised use

10.1039/c5lc00706b 23 RenN.LiuQ.YanL.HuangQ

Preclinical studies have showed that PDE inhibitors, such as sildenafil and cilostazol, can decrease tissue pathology, accelerate bacterial clearance, and reduce the time to lung sterilization in M.tb -infected mice when used in combination with standard TB therapy [33]