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The breakthrough came when Chen and colleagues (Sun et al., 2013) discovered that cytosolic DNA triggers the synthesis of a cyclic dinucleotide, cyclic GMP-AMP (cGAMP)

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doi: 10.1055/s-0042-104060

Redox potential assessed by cyclic voltammetry ROS production involves cycling between Cu(I) and Cu(II) states, so we reasoned that the difference in ROS production between the different Cu:peptide complexes might be related to the energetics of this transition