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Chemical Class: Synthetic heptapeptide analog of -MSH (melanocortin peptide) IUPAC Name (peptide form): Ac-Nle-cyclo[Asp-His-D-Phe-Arg-Trp-Lys]-OH Peptide Sequence (cyclic): Ac-Nle-Asp-His-D-Phe-Arg-Trp-Lys-OH (Cyclized through AspLys side-chain lactam bridge) Molecular Formula: CHNO Molecular Weight: 1025.2 g/mol Structural Features: Heptapeptide N-terminal acetylation Side-chain lactam (AspLys) macrocycle Contains non-canonical amino acids: Nle (norleucine) and D-Phe Designed for high affinity and selectivity toward MC3R and MC4R receptors This product is intended solely for laboratory research purposes

Methods Materials For NMR spectra of compounds in this manuscript, see Supplementary Figs 1473

Delayed gastric emptying may influence: Meal tolerance Frequency of eating Nausea severity Portion size But current evidence does not support clinically significant malabsorption solely due to gastric slowing

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