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Overall, our results demonstrate that oxygen-to-sulfur (O-to-S) exchange provides a versatile electrophile tailoring strategy for late-stage optimizations, leading to the discovery of -chlorothioacetamides and -fluorothioacetamides as electrophilic warhead chemotypes

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doi: 10.1002/path.4454 107 Grigoletto FernandesI.Alves de BritoC.Silva Dos ReisV

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Proper handling and storage are important for preserving glutathione in its reduced form, minimizing oxidation, and supporting the integrity and reproducibility of laboratory research