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10.1046/j.1365-3040.2003.01016.x 90 MittovaV.VolokitaM.GuyM.TalM

Pain-related pathology, especially pain of an unknown etiology, is a significant challenge in clinical practice, and the limitations of traditional pain-relief mechanisms have made it necessary to explore alternative approaches

The free peptide was first identified in human plasma in 1973, and the copper-bound form was recognized shortly afterward as the biologically relevant species in most contexts where the tripeptide has been characterized

It's surface action versus pore action

Orally administered glutathione is suggested to serve as a source of amino acids in the synthesis of endogenous glutathione

However, be aware that dietary sources of glutathione tend to be poorly absorbed by the body