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A second alternative might be that cereulide synthesis follows the classical collinear principle of NRPS product assembly including partial hydrolysis of the preformed tetradepsipetides, mediated by condensation domain reversibility

Tumor cells can upregulate these checkpoints to evade immune surveillance, and in some cases, they also activate oncogenic signaling pathways

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(2020) 10:e032321

Metabolites and cofactors of the -glutamyl cycle and trans-sulphuration pathway Data from key studies of metabolites of the -glutamyl cycle and trans-sulphuration pathway is shown in Figures 4, 5 and 6 and a summary of additional studies presented in Table 9