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Tobacco-specific nitrosamines Tobacco-specific nitrosa mines, in clud ing 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone or nicotine-derived NNK, NNN, nitrosaminoaldehyde (NNAL), N -nitrosoanatabine (NAT), N -nitrosoanabasine (NAB), iso-NNAL, and iso- N -nitrosamino acids (iso-NNAC), are non-volatile, present in unburned tobacco leaves and tobacco smoke, and pro-carcinogenic